Blair and Chuck are, arguably, the most iconic couple of the Gossip Girl series. But where do they make out for the first time?

Answer In a limousine

In the episode "Victor, Victrola" Chuck challenges Blair to enter the stage of his burlesque club, and she pleasantly shocks him by dancing. At the end of the night, he drives her home in a limo and they end up hooking up for the first time in the series!

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