Angelina Jolie was famous before she met her third husband, but their affair during the filming of "Mr. and Mrs. Smith" became the talk of Hollywood. Who was he?

When Angelina Jolie and Brad Pitt coupled onscreen to play married spies who didn't know the other's career, the heat generated by their chemistry was unmistakable. The rumors led to Pitt's divorce from then-wife, Jennifer Aniston. Both Jolie and Pitt deny they were involved in a physical relationship while Pitt was still married. Jolie and Pitt then married years later.

Asked by Jennifer Sinclair · Last updated 5 years ago · 27.3K views · SOURCE